Di-μ-oxido-bis{[(R,R)-(+)-1-amino-2-(3-methoxy-2-oxidobenzylideneamino-κ2 O 2,N)-1,2-diphenylethane-κN]oxidovanadium(V)} dihydrate
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چکیده
In the crystal structure of the title compound, [V(2)(C(22)H(21)N(2)O(2))(2)O(4)]·2H(2)O, oxide-bridged dimers of the complex are linked to water mol-ecules by hydrogen-bonding inter-actions. The two five-membered chelate rings in the dimeric mol-ecule both adopt twist conformations. Each V(V) atom is six-coordinated by one oxide group and by two N and one O atom of the tridentate Schiff base ligand, and is bridged by two additional oxide atoms. The metal centre has a distorted octa-hedral coordination. The monoanionic ligands occupy one equatorial and two axial positions.
منابع مشابه
Di-μ-oxido-bis({(R)-(–)-2-[1-(2-aminopropylimino)ethyl]-1-naphtholato-κ3 N,N′,O}oxidovanadium(V))
In the title dinuclear compound, [V(2)(C(15)H(17)N(2)O)(2)O(4)], each V(V) atom is six-coordinated by one oxide group, and by two N and one O atom of the tridentate Schiff base ligand, and bridged by two additional oxide O atoms, resulting in a centrosymmetric dimer. The metal centre has a distorted octa-hedral coordination with the monoanionic Schiff base ligand occupying one equatorial and tw...
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